Types and concentrations of tire wear particles (TWPs) in road dust generated in slow lanes.

Drivers commonly navigate their vehicles at moderate speeds in proximity to traffic lights. In this study, road dust samples were collected in the vicinity of traffic lights, as well as at a taxi stand (TS) situated between traffic lights, with considerations given to both forward direction (FD) and backward direction (BD). The characterization of tire wear particles (TWPs) in the road dust was meticulously conducted based on particle size. Notably, tire-road wear particles (TRWPs) were conspicuously absent in samples surpassing 500 µm. Furthermore, TRWPs comprised less than 1% of identified particles in the road dust samples of 212-500 µm, with their origin traceable to heavy vehicles rather than passenger cars. The abundance of TRWPs from heavy vehicles exhibited marked variations, with heightened prevalence in the TS and BD samples as opposed to the FD sample. For the samples smaller than 212 µm, the composition of natural rubber (NR) in TWPs demonstrated a diminishing trend with escalating particle size. Conversely, the composition of styrene-butadiene rubber (SBR) exhibited an upward trajectory independent of the sampling site. The NR composition ratio in TWPs followed the order: TS (17-55%) > FD (17-47%) > BD (13-36%), while the SBR composition ratio exhibited the sequence: BD (62-86%) > FD (48-79%) > TS (24-70%). The TWP concentrations in road dust obtained from the TS (0.35-0.82%) were discernibly lower than those in the FD (0.54-1.77%) and BD (0.61-1.29%) samples. Specifically, the average TWP concentrations in road dust samples, falling within the size range of 20-212 µm, were 0.45%, 1.06%, and 0.91% for the TS, FD, and BD samples, respectively. These concentrations were lower than the corresponding values observed in samples collected from a bus stop.

Variation in Abundance Ratio of Isoprene and Dipentene Produced from Wear Particles Composed of Natural Rubber by Pyrolysis Depending on the Particle Size and Thermal Aging.

Tire wear particles (TWPs) are generated by friction between the road and the tire. TWPs are one of the major microplastics found in environmental samples, such as road dust, particulate matter (PM), and sediment. TWP contents in environmental samples are generally analyzed using the pyrolysis technique. Tire tread compounds of heavy vehicles are usually composed of natural rubber (NR). Isoprene and dipentene are the principal pyrolysis products of NR, and dipentene is employed as the key marker for the determination of the TWP contents. In this study, an NR abrasion specimen was thermally aged, and an abrasion test was performed to obtain the wear particles. The influence of the wear particle size and thermal aging on the pyrolysis behavior of NR was investigated. The isoprene/dipentene ratio exponentially increased as the wear particle size decreased, and it was also increased by the thermal aging of the abrasion specimen. The increased isoprene/dipentene ratio by thermal aging was explained by increasing the crosslink density. Using the relationship between the wear particle size and the isoprene/dipentene ratio, it is possible to estimate the isoprene/dipentene ratio for very small TWP such as PM. The experimental results concluded that the wear particle size and thermal aging affect the formation of the key pyrogenic products, and the influencing factors should be considered for the quantification of TWP contents in the environmental samples.

Classification and Characterization of Tire-Road Wear Particles in Road Dust by Density.

Tire treads are abraded by friction with the road surface, producing tire tread wear particles (TWPs). TWPs combined with other particles on the road such as road wear particles (RWPs) and mineral particles (MPs), forming tire-road wear particles (TRWPs). Dust on an asphalt pavement road is composed of various components such as TRWPs, asphalt pavement wear particles (APWPs), MPs, plant-related particles (PRPs), and so on. TRWPs have been considered as one of major contaminants produced by driving and their properties are important for study on real abrasion behaviors of tire treads during driving as well as environmental contamination. Densities of the TRWPs are totally dependent on the amount of the other components deposited in the TWPs. In this study, a classification method of TRWPs in the road dust was developed using density separation and the classified TRWPs were characterized using image analysis and pyrolytic technique. Chloroform was used to remove APWPs from mixture of TRWPs and APWPs. TRWPs were found in the density range of 1.20-1.70 g/cm3. By decreasing the particle size of the road dust, the TRWP content in the road dust increased and its density slightly tended to increase. Aspect ratios of the TRWPs varied and there were many TRWPs with low aspect ratio below 2.0. The aspect ratio range was 1.2-5.2. Rubber compositions of the TRWPs were found to be mainly NR/SBR biblend or NR/BR/SBR triblend.

Quantification of tire tread wear particles in microparticles produced on the road using oleamide as a novel marker.

In general, tire tread rubber compounds contain oleamide for improvement of manufacturing processibility, mold release characterization, and abrasion resistance. Tire tread wear particles (TWPs) are one of major contributors to microplastic emissions. In this study, a novel analytical method for quantification of TWP in microparticles produced on the road (road dust, MPRs) was developed by employing oleamide as a new marker. MPRs were collected at bus stops in autumn, winter, and summer seasons. MPRs of 38-63, 63-106, 106-212, and 212-500 µm obtained by size separation were employed for the analysis. Rubber components for bus and passenger car tire tread compounds were identified using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Oleamide was extracted from the MPRs with acetone and was identified using GC/MS. The oleamide concentration was analyzed using GC equipped with flame ionization detector (FID). The TWP contents of the MPRs were determined using the oleamide concentrations and the reference compound formulations. In order to reduce the sampling errors, each experiment was carried out five times and the results were averaged. The TWP contents of the MPRs were 1.4-4.7 wt% and were different according to the sampling seasons and places. The TWP contents were increased by increasing the traffic volume and the temperature.